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What is water and hydrogen electrolysis? Electrolyzers and their applications
Have you ever wondered how from a simple chemical compound like water, you can obtain pure hydrogen and oxygen? Electrolysis of water is a fascinating process that allows for the breakdown of water molecules into their basic components using electrical energy. This not only enables us to produce the fuel of the future but also contributes to environmental protection by reducing harmful gas emissions.
Last updated: August 25, 2025
In this article, you will learn…
- What is water electrolysis?
- What is electrolysis chemistry - reaction and chemical basics?
- What is water electrolysis about – colors and theirmeaning?
- What is water electrolysis - what precipitates?
- What is hydrogen electrolysis - hydrogen production through electrolysis?
- What are electrolyzers - what are they and how do they work?
- What is an electrolyzer for water - types?
- What is a PEM electrolyzer (proton exchange membrane)?
- What are home hydrogen electrolyzers?
- What is an alkaline electrolyzer?
- What is a SOEC electrolyzer (solid oxide electrolysis)?What is the application of electrolysis and electrolyzers?
What is water electrolysis?
Water electrolysis is a process in which we decompose water into hydrogen and oxygen using electrical voltage. It is one of the key chemical processes occurring in modern energy and chemical industries. In practice, this means thatBy passing current through water containing an electrolyte, we can obtain high-purity gases that have a wide range of applications in various industries.
Electrolysis can be compared to separating ingredients in a blender. When you turn on the blender, the ingredients mix and separate into different parts. Similarly, electric current in electrolysis mixes water and then separates it into hydrogen and oxygen, which we can use as needed.
Electrolysis chemistry - reaction and chemical basics
During the electrolysis of water, a reaction occurs in which water (H₂O) dissociates into hydrogen ions (H⁺) and hydroxide ions (OH⁻). At the cathode, which is the negative electrode, hydrogen ions are reduced, leading to the formation of gaseous hydrogen. At the anode, which is the positive electrode, hydroxide ions are oxidized, resulting in the formation of gaseous oxygen andwater.
The key in this process are the secondary transformations of ions and proton exchanges. Protons (H⁺) move towards the cathode, where they are reduced to gaseous hydrogen. It's a bit like passing the baton in a relay race – protons transfer energy, enabling continuous reactions.
Electrolysis of water – colors and their significance
During the electrolysis of water, various colors can be observed, which indicatethe presence of specific substances or contaminants:
- Colorless – indicates pure distilled water without contaminants.
- Greenish – presence of copper ions; this may indicate corrosion of copper electrodes.
- Brownish – suggests the presence of iron ions, which may result from electrode corrosion.steel.
- Yellowish – may indicate the presence of chloride ions or other halogen compounds.
These colors are like traffic signals for a chemist – they inform about what is happening in the solution and whether the process is proceeding correctly.
Electrolysis of water - what precipitates?
During the electrolysis of water, various substances may precipitate, mainly inthe formation of deposits on the electrodes. These can be metal oxides originating from the electrodes or impurities present in the water. The precipitation of deposits can affect the efficiency of the process, which is why it is important to use clean water and appropriate electrode materials to avoid unwanted by-products.
Hydrogen electrolysis - hydrogen production through electrolysis
Electrolysis plays a key role in the production of green hydrogen, which isrecognized as fuel of the future. By utilizing energy from renewable sources, such as the sun or wind, we can produce hydrogen without carbon dioxide emissions. In this process, water is split into gaseous oxygen and hydrogen, which can be used in industry, energy, or transportation.
The use of renewable energy in the electrolysis process allows for the minimization of the carbon footprint and promotes sustainable development. Hydrogen producedin this way can be used in fuel cells to power vehicles or store energy.
It's worth remembering: Water electrolysis is a key process in the production of green hydrogen, which has potential in energy transformation.
The difference between water electrolysis and hydrogen electrolysis is that in the case of water electrolysis, we break down water into hydrogen and oxygen, while electrolysisHydrogen refers to the processes of purifying or splitting existing hydrogen. Hydrogen electrolysis is less common and usually pertains to specialized applications in laboratories or the chemical industry.
Electrolyzers – what are they and how do they work?
A device for water electrolysis, or electrolyzer, is equipment that allows the electrolysis process to be carried out under controlled conditions.It works on the principle of electric current flow through water containing an electrolyte.
This device contains two electrodes: a positively charged electrode (anode) and a negatively charged electrode (cathode). Under the influence of electric voltage, ions in the solution move to the respective electrodes, where redox reactions occur, leading to the release of hydrogen and oxygen.
Water electrolyzer -types
There are several types of electrolyzers, differing in technology and application. The choice of the appropriate type depends on the user's needs and the specifics of the application.
PEM Electrolyzer (Proton Exchange Membrane)
It uses a membrane for the transport of proton ions (H⁺) between the anode and cathode. PEM electrolyzers are characterized by:
- High efficiency – fast response time and high purity of produced hydrogen.
- Compact design – ideal for applications where space is limited.
- Safety – separates hydrogen and oxygen, minimizing the risk of gas mixing.
Home-based
Produces green hydrogen in home conditions. Such devices can be powered by energy from solar panels or wind turbines, making them an eco-friendly solution for households striving for energy self-sufficiency. However, it is important to keep in mind:
- Safety – hydrogen is a flammable gas, so the installation mustmeet the appropriate standards.
- Costs – investing in equipment can be significant, but it pays off in the long run.
- Legal regulations – local regulations regarding the production and storage of hydrogen should be checked.
Alkaline electrolyzer
Utilizesalkaline solutions, such as KOH or NaOH, as an electrolyte. This is a proven and cost-effective technology, often used in the industry.
SOEC (Solid Oxide Electrolysis Cell)
Utilizes solid oxides as an electrolyte and operates at high temperatures. It is characterized by high energy efficiency.
The application of electrolysis and
Electrolysis and electrolyzers have a wide range of applications in various fields of industry and everyday life. Here are some key areas where they are used:
Application of electrolysis in industry
Electrolysis is used in the chemical industry for the production of chlorine, caustic soda, aluminum, and many other substances. IntegrationThe process of electrolysis from renewable energy sources allows for the reduction of greenhouse gas emissions and promotes sustainable development. Example applications include:
- Metal production – obtaining pure metals from their ores through the electrolysis of molten salts.
- Water purification – removing contaminants and disinfection by generating ozone and others.oxidizing agents.
- Pharmaceutical industry – synthesis of high-purity chemical compounds.
Water electrolysis at home – possibilities and limitations
In home conditions, electrolysis can be used for:
- Hydrogen production – up tofuel cell power supply in small devices.
- Water purification – by removing heavy metals and other contaminants.
- Educational purposes – demonstrations of chemical processes for students and science enthusiasts.
Limitations include:
- Safety – risks associated with electricity and gases.
- Efficiency – household appliances may be less efficient than their industrial counterparts.
- Operating costs – electricity consumption and consumables.
Electrolysis -depilation and other unusual applications
Electrolysis has also found application in cosmetology, particularly in permanent hair removal. This method involves inserting a thin needle into the hair follicle and passing an electric current that destroys the hair root. The advantages of this method are:
- Permanent hair removal – effectiveness independent of hair color andskins.
- Precision – the ability to remove individual hairs.
- Safety – when performed correctly, it is safe for the skin.
However, the process is time-consuming and can be somewhat painful, which is worth considering.
Types of electrolysis
Electrolysis can involve various substances and occur in different ways, depending on the electrolyte used and the conditions of the process. Here are some main types of electrolysis:
It's worth remembering: The electrolysis process is complex but fundamental for understanding the production of hydrogen and oxygen.
- Electrolysis of molten salts – a process that involvesthe decomposition of molten salts into their constituent elements. At high temperatures, salt melts, and the ions become mobile. Electric current causes each electrode to attract the appropriate ions, leading to the release of pure metals or nonmetals.
- Electrolysis of NaCl (sodium chloride) – in an aqueous solution of sodium chloride, or table salt, electrolysis results in the production of chlorine, hydrogen, and caustic soda. Substances capable ofconductivity of electricity in the solution allows for an efficient process flow.
- Electrolysis of HCl (hydrochloric acid) – during the electrolysis of hydrochloric acid, we obtain chlorine and hydrogen. This is important in the production of chemicals and in the purification of raw materials.
- Electrolysis of KOH and NaOH (hydroxides) – uses potassium hydroxide (KOH) or sodium hydroxide (NaOH) as an electrolyte. In an aqueous solution, theseHydroxides dissociate into ions, which allows for the conduction of electricity. An alkaline electrolyzer is often used for the industrial production of hydrogen and oxygen.
Electrolysis - summary
Electrolysis is an extremely important chemical process that finds applications in many areas of our lives. From the production of green hydrogen, through the chemical industry, to cosmetology – the possibilities are nearly limitless.Through the process of electrolysis, we can strive for a more sustainable future by reducing harmful gas emissions and promoting renewable energy sources.
So is electrolysis the key to the world's energy future? Everything suggests that it is. With the continuous development of technology and increasing efficiency of processes, electrolysis is becoming more accessible and cost-effective. It is a fascinating field of science that combineselements of chemistry, physics, and engineering, offering unlimited possibilities for those who want to explore its secrets.
Frequently Asked Questions (FAQ)
What is water electrolysis?
Water electrolysis is the process of breaking down water into hydrogen and oxygen using electrical energy.
What are the applications of electrolysis?
Electrolysis is used in the chemical industry, hydrogen production, water purification, and cosmetology.
How do electrolyzers work?
Electrolyzers operate on the principle of electric current flowing through water with an electrolyte, leading to chemical reactions that release gases.
What types of electrolyzers are there?
Types of electrolyzersinclude PEM, alkaline, and SOEC electrolyzers, differing in technology and application.
Is electrolysis safe?
Yes, but it requires adherence to appropriate safety standards, especially in the context of flammable gases.
What are the limitations of home electrolysis?
Limitations include safety, device efficiency, and costs.exploitation.
Author: Maciej Waliduda — water treatment specialist with experience in water technology applications.
